Synthesis and Characterization of Some 1,2,4-Triazol-4-Amino Schiff Bases of Decorated Nano Reduced Graphene Oxide With 2-Naphthol-4-Sulfonic Acid as Non-Toxic Compounds
DOI:
https://doi.org/10.47604/ijns.2934Keywords:
Graphene Oxide, 1,2,4-triazole, 1,2,4-triazol-4-amino Schiff Bases.Abstract
Purpose: This research, some derivatives were Synthesis and Characterization of Some 1,2,4-triazol-4-amino Schiff Bases of Decorated Nano Reduced Graphene Oxide with 2-naphthol-4-sulfonic acid .
Methodology: In by the hummer method preparing the graphene oxide (GO) and then reducing it to the reduced graphene oxide (RGO), Then prepare the corresponding and decorated derivative with 2-naphthol-4-sulfonic acid, Using the electric method (ArNRGO) in two steps, first one preparing the disonium salts and the second, electrical decoration, Prepare the corresponding Triazole derivative (ArNRGOTZ) by thermal fusion for the Ar-NRGO Aromatics Derivative with Thiocarbozide (TC), Also, ArNRGOTZS (3-1) nanoschiff bases prepared by heat mixing between ArNRGOTZ with 4-Nitrobnzaldehyde, 4-Chlorobenzaldehyde and 4-Methoxybenzaldehyde,
Findings: The data characterization by IR, XRD and SEM infrared spectroscopy with stability evaluation from TGA, DSC and DTG measurements.
Unique Contribution to Theory ,Practice, and Policy: Formation of 1,2,4-triazol-4-amino Schiff Bases of Decorated Nano Reduced Graphene Oxide with 2-naphthol-4-sulfonic acid as non-toxic compounds To benefit from them in the future as chemical compounds that transport drugs inside the living cell.
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References
Ekimov, A. I. (1981). Quantum size effect in three-dimensional microscopic semiconductor crystals. Jetp Lett., 34, 345.
Singu, D. C., Joseph, B., Velmurugan, V., Ravuri, S., & Grace, A. N. (2018). Combustion synthesis of graphene from waste paper for high performance supercapacitor electrodes. International Journal of Nanoscience, 17(01n02), 1760023.
Thickett, S. C., & Zetterlund, P. B. (2013). Functionalization of graphene oxide for the production of novel graphene-based polymeric and colloidal materials. Current Organic Chemistry, 17(9), 956-974.
Verdejo, R., Bernal, M. M., Romasanta, L. J., & Lopez-Manchado, M. A. (2011). Graphene filled polymer nanocomposites. Journal of Materials Chemistry, 21(10), 3301-3310.
K. Potts, Chem. Rev., 61, 87 (1961).
Whiteley, M. A., & Yapp, D. (1927). LXXVII.—The reaction between diazonium salts and malonyldiurethane. Journal of the Chemical Society (Resumed), 521-528.
G. Pellizari, Gazz. Chim. Ital (1911) 20,93.
I.L. Finar (1921) "Organic Chemistry, Stereochemistry, and Chemistry of Natural Products", 5th ed., London, 2, I.
M. Clemons, R.E. Coleman, S. Verma.(2004). Cancer Treat Rev., 30, 325.
M. Amir, S. Shahani, Ind. (1998). J. Hetrocycl. Chem. ,8(2), 107 .
G.S. Grambaryan, Izv. S. Kh. Nauk. (1998).26, 40 .
R Mohamed, S. (2009). Synthesis of some substituted 1, 3, 4-oxadiazoles, thiadiazoles and 1, 2, 4-triazoles. Journal of Education and Science, 22(2), 29-37.
S.B. Dawane, G.S. Konda, M.B. Shailkh, S.S. Chobl, T.N. Khandare, T.V. Kamble, B.R. Bhosale.(2010). Molecules, 18, 466 .
UV, I. (2013). Synthesis of Some Substituted 1, 3, 4-Oxadiazoles, Thiadiazoles and 1, 2, 4-Triazoles from Acid Chlorides.
Jubair Ahmed M., Abdulwahhab Ghazwan H. (2019). "Synthesis and characterization of some new imine graphene derivatives", MSC Thesis, College of Education for Pure Science, University of Tikrit.
Tang, L., Yang, Z., Duan, F., & Chen, M. (2017). Fabrication of graphene sheets/polyaniline nanofibers composite for enhanced supercapacitor properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 520, 184-192.
M. Brahmayya, S. Suen, S.A. Dai, J. Taiwan Inst.(2018) Chem. Eng., 83, 174-183 .
Martínez-García, G., Agüí, L., Yáñez-Sedeño, P., & Pingarrón, J. M. (2017). Multiplexed electrochemical immunosensor for obesity-related hormones using grafted graphene-modified electrodes as platforms for antibodies immobilization. Procedia technology, 27, 187-189.
N.A. Rasheed, B.I. Al-Abdali, J. Global Pharma Tech.(2018) 10(03), 417-430 .
H.M.S. Al-Jubori, Ph.D. Thesis, College of Education for Pure Sciences, University of Tikrit (2015).
Namvari, M., & Namazi, H. (2014). Sweet graphene I: toward hydrophilic graphene nanosheets via click grafting alkyne-saccharides onto azide-functionalized graphene oxide. Carbohydrate research, 396, 1-8.
Ansón-Casaos, A., Puértolas, J. A., Pascual, F. J., Hernández-Ferrer, J., Castell, P., Benito, A. M., ... & Martínez, M. T. (2014). The effect of gamma-irradiation on few-layered graphene materials. Applied Surface Science, 301, 264-272.
Rajagopalan, R. (2017). Nasicon based materials for high voltage lithium-ion and sodium-ion batteries.
Vagdevi, K., Devi, V. R., & Rao, K. V. (2017). First principles study of tunable band gap in bi layer Graphene (BLG). Materials Today: Proceedings, 4(8), 7586-7591.
Yadav, N., & Lochab, B. (2019). A comparative study of graphene oxide: Hummers, intermediate and improved method. FlatChem, 13, 40-49.
Shalaby, A., Nihtianova, D., Markov, P., Staneva, A. D., Iordanova, R. S., & Dimitriev, Y. B. (2015). Structural analysis of reduced graphene oxide by transmission electron microscopy. Bulgarian Chemical Communications, 47(1), 291-295.
Mir, A., & Shukla, A. (2018). Bilayer-rich graphene suspension from electrochemical exfoliation of graphite. Materials & Design, 156, 62-70.
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